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Topic 13 Learning Objectives

Be able to:

Define, compare and contrast, classify, differentiate, put in order, predict using, identify correct and incorrect examples of, identify correct and incorrect interpretations of, identify correct and incorrect applications of…the following terms:

        chemical kinetics
   
     reaction rate
   
     average rate
   
     instantaneous rate
   
     rate constant
   
     rate law
   
     reaction order
   
     half life
   
     collision theory
   
     activation energy
   
     activated complex
   
     collision theory
   
     Arrhenius equation
   
     reaction mechanism
   
     elementary step
   
     reaction intermediate
   
     molecularity
   
     unimolecular
   
     bimolecular
   
     termolecular
   
     catalyst
   
     inhibitor
   
     homogeneous catalysis
   
     heterogeneous catalysis
   
     enzyme catalysis
   
     active site
   
     substrate

 

Analyze and apply the factors that affect reaction rate

Relate the rate of disappearance of a reactant and the rate of appearance of a product from the balanced equation

Determine the average reaction rate from concentration measurements at specific times

Give the reaction order with respect to each reactant and give the overall reaction order for a reaction when given its rate law

Determine the rate law from initial concentrations and initial rates

Work rate problems using concentration-time laws for both first order and second order reactions

Calculate half-lives for both first order and second order reactions

Use graphing to determine the order of a reaction

Use collision theory and energy considerations to explain reactions and reaction rates

Explain reactions and reaction rates using potential energy profiles, including activation energy and the activated complex

Use collision theory and energy considerations to explain the effect of temperature, surface area, concentration, and the presence or absence of a catalyst on reaction rates

Use the Arrhenius equation to describe the relationship among activation energy, temperature, frequency of collisions, and the rate law constant and to calculate these values

Describe reaction mechanisms in terms of elementary steps, reaction intermediates, and molecularity

Write the overall balanced equation from the mechanism

Write rate laws for elementary steps

Write rate laws from mechanisms

Determine the rate-determining step from the rate law

Describe the nature of a catalyst and catalysis, including enzyme catalysis