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Topic 8 – Ionic and Covalent Bonding

Download full set of notes for Topic 8 (MS Word 2000)

LEWIS ELECTRON-DOT SYMBOLS AND STRUCTURES
Lewis electron-dot symbols for atoms and monoatomic ions
Definition
Conventions
Examples
Lewis electron-dot structures for molecules and polyatomic ions
Definition
The octet rule
Guidelines for drawing Lewis electron-dot structures for molecules and polyatomic ions – the “Bucket Method”
Examples
METALLIC BONDING
Definition
Responsible for properties of metals
IONIC BONDING
Definition
Electron configuration of ions
Using Lewis electron-dot structures to describe ionic bonding
COVALENT BONDING
Covalent bond
Definition
Using Lewis electron-dot structures to describe covalent bonding
Coordinate covalent bond
Definition
Once formed, indistinguishable
Shown as an arrow
Using Lewis electron-dot structures to describe coordinate covalent bonding
Bond order and the types of covalent bonds described
Definition
Bond orders and their type of bond
Bond length
Depends on bond order
Examples
Delocalized bonding and resonance bonding
Definitions
Delocalized bonding
Resonance description
Resonance bonding
Resonance forms
The mule: a model for resonance
Examples 
Exceptions to the octet rule
Odd number of electrons
Central atom has fewer than eight electrons
Central atom has more than eight electrons
BOND TYPES ACCORDING TO ELECTRONEGATIVITY
Ionic bonds
Descriptions
Definition
E.D. equal to or greater than 2.0
Polar covalent bonds
Description
E.D. greater than 0.4 and less than 2.0
Polar molecules contain one or more polar covalent bonds
Nonpolar covalent bonds
Descriptions
E.D. equal to or less than 0.4
FORMAL CHARGE AND LEWIS STRUCTURES
Definition
Description
Rules for assigning electrons to calculate the formal charge on an atom
Calculating the formal charge on an atom
Determining which Lewis electron-dot structure is best if more than one is possible